Ok firstly, create a new layer above the layer with your interface.
Set your foreground colour to: #C1C2C4.
Now select the Ellipse tool (note this is the shape tool not the marquee tool).
Ok now roughly where you want your button to appear, hold SHIFT and drag your circular shape to the size you want.
Ok now to give the button the chrome effect add the following layer styles.
Firstly add an
Inner shadow with these settings:
Blend mode normal, colour white, opacity 29, angle -81, distance 2, choke 0, size 0.
Now add an Inner Glow:
Settings missing.
Next up add a Gradient Overlay:
Blend mode screen, opacity 81, colour- gradient (black-white), style linear, angle 90, scale 49.
And last but not least add a Stroke:
Settings missing.
When your done, you may want to save your layer style for later use.
Click ok when your done. You should be left with a button similar to the one shown opposite.